- Sullivan grew up and attended Calvary Christian College high school in Logan Queensland (near Brisbane). Her father is an importer of medical equipment, and her mother is a visual artist. She has family overseas, particularly in Britain, where Sullivan's parents emigrated from.
- In 2014, she appeared in the feature film Galore, which premiered at the Melbourne International Film Festival and screened at the Berlin International Film Festival. She earned a Best Supporting Actress award at Cinema des Antipodes Saint-Tropez.
- Lily has also appeared in the second season of the television series Rake and in the NBC series Camp. She has a role in Sucker, which was released in late 2015.
- Sullivan made her feature film debut in P. J. Hogan's 2012 feature Mental, earning an AACTA Award nomination for Best Young Actor and a Film Critics Circle of Australia Award nomination for Best Performance by a Young Actor.
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