- Began a relationship with Emmerdale Farm (1972) co-star Matthew Wolfenden in November 2007, got engaged in December 2009, and then broke up in August 2013. They later reconciled in April 2014, married in February 2018 before separating permanently in November 2023. They have three children together.
- Served as bridesmaid at the wedding of her half-brother Jamie Lomas to Kym Marsh (2 September 2012).
- Her 1st acting role was at the age of 8 in a stage production of "Bugsy Malone".
- Attended Philips High School in Bury, Manchester.
- Gave birth to her first child at age 22, a son named Buster Lawrence Wolfenden on April 3, 2010. Child's father is her fiancé (now husband), Matthew Wolfenden.
- Gave birth to her second child at age 27, a son Bowie Grey Wolfenden on December 19, 2015. Child's father is her boyfriend (now husband), Matthew Wolfenden.
- Was eight months pregnant with her son Bowie when she took maternity leave from filming Emmerdale Farm (1972).
- Is just 28 years younger than Sally Dexter, who plays her grandmother on Emmerdale Farm (1972).
- Gave birth to her third child at age 31, a son Ace Gene Wolfenden on July 26, 2019. Child's father is her husband, Matthew Wolfenden.
- Married her boyfriend of 11 years Matthew Wolfenden in a surprise ceremony - the 100 guests had been told they were attending Webb's 30th birthday party instead - held at Ripley Castle, Yorkshire, wearing a bespoke semi-sheer lacy gown. Her brother Jamie Lomas walked her down the aisle whilst her sister Cassie and Emmerdale Farm (1972) co-stars Emma Atkins, Lucy Pargeter, Zoë Henry, Charlotte Bellamy, Sammy Winward and Roxy Shahidi served as bridesmaids. The couple's two sons, Buster and Bowie, served as page boys.
- Is the half-sister of Cassie, Kelly and Jamie Lomas, all from her mother's previous relationship, and the sister of Lucy and Daniel Webb.
- Is the aunt of Billy (b. 2005), the late Archie Jay (b. 2009, d.2009) and Polly (b. 2011), all via her half-brother Jamie Lomas.
- Her Emmerdale Farm (1972) character Debbie Dingle became the 16th woman on the soap opera to give birth. Debbie had a daughter Sarah (played initially by Sophia-Amber Moore and later Katie Hill), born on June 6, 2005, and a son Jack (played by Seth Ball), born on October 16, 2012.
- Is one of 5 British soap actresses to have acted out giving birth in a live episode. The others are Jennie McAlpine (Fiz Stape in Coronation Street (1960) on 9 December 2010), Danielle Harold (Lola Pearce in EastEnders (1985) on 23 July 2012), Sian Reese-Williams (Gennie Walker in Emmerdale Farm (1972) on 17 October 2012) and Tameka Empson (Kim Fox-Hubbard in EastEnders (1985) on 19 February 2015).
- Returned to work eleven months after giving birth to her son Bowie to resume filming Emmerdale Farm (1972).
- Was nine months pregnant with her son Ace when she went on maternity leave from filming Emmerdale Farm (1972).
- Returned to work five months after giving birth to her son Buster in order to resume filming Emmerdale Farm (1972).
- Delivered all three of her sons naturally. Bottle-fed her son Buster as she was unable to produce enough milk but went on to breastfeed sons Bowie and Ace.
- Announced on November 22, 2023 that she and Matthew Wolfenden had separated after 5 years of marriage. They had been together on and off for 15 years.
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