- Made Grand Ole Opry debut on June 30, 2000.
- Graduated with highest honors with a Bachelor of Science degree in biology with a major in chemistry from the University of Northern Alabama. Worked in the chemical industry prior to pursuing a career in country music.
- Holds an annual Charity Foundation Event called "Tennessee River Run", which benefits the Darryl Worley Foundation, a not-for-profit organization that contributes funds to the areas surrounding Hardin County, St. Jude Research Hospital, Le Bonheur Children's Medical Center and the Cystic Fibrosis Foundation.
- At the age of 43, Darryl became a father. Baby Savannah Gail Worley was born on Monday, March 24, 2008 at 10:26 pm. Savannah weighed in at 6 lbs, 6 oz and was 19 3/4 inches long.
- Posed nude (non-full-frontal) for the July 2007 issue of Playgirl magazine.
- Has two brothers, Tommy and Barry.
- Had opened a restaurant, the Worleybird Cafe, in Savannah, Tennessee, with his ex-wife Beverly.
- His father was a Methodist preacher and his mother sang in the church choir.
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