As the names of the characters suggest this is something of a parody of Washington Irving's The Legend of Sleepy Hollow.
The guitar Chester plays is a CF Martin, possibly an 18 series model.
This episode aired in February 1962, and in it, Chester teaches Sue Ane Langdon's character how to play the guitar. In April of that same year, Sue Ane is taught again, but by Andy on The Andy Griffith Show (1960).